池州肉聯(lián)廠食品污水沉淀劑pam聚合氯化鋁報價廢水凈化pac廠家 |
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價格:19002 元(人民幣) | 產(chǎn)地:河南 |
最少起訂量:1噸 | 發(fā)貨地:河南 | |
上架時間:2020-08-04 17:57:59 | 瀏覽量:110 | |
河南安家凈環(huán)保科技有限公司
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經(jīng)營模式:生產(chǎn)加工 | 公司類型:私營獨資企業(yè) | |
所屬行業(yè):水處理化學(xué)品 | 主要客戶:污水廠 | |
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聯(lián)系人:曹先生 (先生) | 手機:18838138890 |
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郵箱:553890753@qq.com | 地址: |
AM聚丙烯酰胺的合成及工藝物理特性:PAM由丙烯腈與水在骨架銅催化劑作用下直接反響生成聚丙烯酰胺再經(jīng)離子交流聚合單調(diào),等工序即得廢品,工藝簡介如下:催化劑:催化水合CH2=CHCN+H2O 濕度 CH2=CHCONH2 聚合nCH2=CHCONH2-引發(fā)劑-CH2CHCONH2![]() ![]() ![]() ![]() 聚丙烯酰胺工業(yè)用處:聚丙烯酸胺(PAM)分子量高、水溶性好、可調(diào)理分子量,并能夠引進(jìn)各種離子基團以得到特定的性能。低分子量是分散資料有效增調(diào)劑或穩(wěn)定劑,高分子量是重要的絮凝劑,它能夠制造出親水而水不溶性的凝膠,它對許多團體外表和溶解物質(zhì)有良可以作為凈水藥劑使用,也可以在造紙領(lǐng)域被當(dāng)做助留劑使用,部分造紙使用草漿纖維較短,細(xì)胞雜質(zhì)較高,導(dǎo)致了紙張強度較差,抄紙過程中濾水困難。對于此問題處理辦法有兩種:機械截留和膠體絮凝。 機械截留類似于過濾作用,它適用于紙張中較長部分纖維,纖細(xì)組分隱藏高的原因無法由此說明,助留劑的助留作用也無法用此解釋; 膠體絮凝作用為:凝聚作用和絮凝作用。分子量較小或者無機鹽、電荷密度較高的聚合物使膠體懸浮液穩(wěn)定性喪失從而發(fā)生絮聚作用稱之為凝聚作用,經(jīng)過電荷中和、異相凝聚和補綴作用幾種方法產(chǎn)生的沉積物。聚合氯化鋁是指聚凝作用中所提到的無機鹽。電荷密度較高的聚合物。 運用聚合氯化鋁處理了造紙進(jìn)程由酸性改為中、堿性規(guī)模,紙漿中的陰離子雜質(zhì)的問題,紙機操作以及紙質(zhì)量的一系列問題,聚合氯化鋁帶有陽電荷,可以有效的控制陰離子的作用,有利于紙張濾水性 改善,聚合氯化鋁極容易在纖維外表形成吸附,還可以將帶有負(fù)電荷的填料和纖維吸附,使細(xì)料的藏著率有效的提高,漿料的濾水功效得到進(jìn)一步的改善好的粘附力。由于以上性能PAM普遍應(yīng)用于絮凝、增稠、減阻、擬膠、粘結(jié)、阻垢等范疇 。 陰離子聚丙烯酰胺依據(jù)不同用處和用戶對產(chǎn)品性能的央求,可選用不同分子量運用。 在工業(yè)廢水處置中,特別是關(guān)于懸浮顆粒、較粗、濃度高、粒子帶陽電荷,水的PH值為中性工堿性的污水如鋼鐵廠廢水,電鍍廠廢水,冶金廢水,洗煤廢水等污水處置效果很好。 在飲用水處置。我國很多自來水廠的水源自江河泥少及礦物質(zhì)含量高,比擬混濁,雖經(jīng)過沉淀處置,但仍達(dá)不到央求,需求投加絮凝劑,才干使水質(zhì)變清,很多自來水廠采用無機絮凝劑,但投加量大,構(gòu)成污泥量增大效果不好,采用陰離子聚丙烯酰胺作絮凝劑,投加量是無機絮凝的50分之一但效果是無機絮凝劑的幾倍至幾十倍,特別是我公司消費的聚丙烯酰胺,剩余單體已抵達(dá)食品級(小于0.05%),接近國外先進(jìn)程度,,對處置飲用水更為合適,關(guān)于有機物污染嚴(yán)重的江河水和陰離子聚丙烯酰胺配合運用效果更好。 聚丙烯酰胺用作淀粉廠及酒精廠的流失淀粉及酒糟的回收。往常很多淀粉廠排出的廢水內(nèi)淀粉很高,排放之后影響環(huán)境,糜費資源,投加PAM,使淀粉沉淀,沉淀物經(jīng)壓濾機壓濾變成餅類可作飼料,酒精廠大量的酒糟就是采用這種工藝加工的,黑龍江某酒精廠就是聚丙烯酰胺作絮凝劑,對酒糟中止回收的而且獲得了很大的經(jīng)濟效益。 聚丙烯酰胺用作油田調(diào)剖堵水的堵水劑,三次采油的驅(qū)油劑。 聚丙烯酰胺用作造紙助劑,PAM在造紙方面用處很普遍,可作為長纖維造紙分散劑,干濕加強劑,助留,助濾劑及造紙廢水的絮凝劑等。 最新型的水處置劑聚丙胺處理污水效果很很好 上機就是不行 因為污泥上不了壓濾機上 沉淀后不能抽上了 污水池里攪拌扇葉太小 加進(jìn)去藥劑 不能重復(fù)反應(yīng) 金總百感交集 試了又試 買了我家的聚丙烯酰胺陰離子 聚丙烯酰胺陽離子 聚合氯化鋁都試了 藥劑真好 機器不行啊 2019年金總又花錢買了個板式壓濾機 還是某某品牌 廣告很多 設(shè)備安裝在了 高于沉淀池2米的的地方 還是出現(xiàn)這個問題 污泥抽不上去 不用藥劑自然沉淀 時間太久用裝載機吧務(wù)你挖出了 金總就是不選擇藥劑 壓濾機濾布每個月?lián)Q兩次 一次1000多塊 就是不用陰離子聚丙烯酰胺 這就是經(jīng)驗啊 設(shè)備安裝出現(xiàn)問題 設(shè)備白買了 洗沙專用聚丙烯酰胺因為其具有極性基因—酰胺基,于借其氫健的效果在泥沙顆粒表面吸附。 2、洗沙專用聚丙烯酰胺因其有很長的分子鏈,大數(shù)量級的長鏈在水中有無窮的吸附表面積,故絮凝效果好,能使用長鏈在顆粒之間架橋,構(gòu)成大顆粒的絮凝體,加快沉降。 3、借助于聚丙烯酰胺的絮凝、助凝,清水處置的泥凝過程中可能發(fā)生雙電 After the polymer coagulant dissolves, the polymer is formed. The structure of polymer is a linear structure. One end of the line pulls out a tiny particle, the other pulls out another tiny particle, and acts as a bridge between two distant particles, which gradually enlarges the particle # and eventually forms a large 聚合氯化鋁的水不溶可以通過溶解聚合氯化鋁來觀察。一般情況下聚合氯化鋁溶解后的水溶液較為渾濁時,就表示聚合氯化鋁中的水不溶物較多,反之溶解后的聚合氯化鋁水溶液越清澈,就表示聚合氯化鋁中的水不溶物含量越低。需要注意的是,聚合氯化鋁在固體狀態(tài)下很難直接分辨聚合氯化鋁中水不溶物的情況。 大多時候聚合氯化鋁的固體在我們進(jìn)行直接觀察時,會因為聚合氯化鋁中有一些顆粒物質(zhì)或者塊狀物,尤其在滾筒型的聚合氯化鋁中存在更多,就異味聚合氯化鋁的產(chǎn)品質(zhì)量不行,其實這是不對的。聚合氯化鋁的水不溶物一般是由于生產(chǎn)原料和生產(chǎn)工藝決定的construction, and do not pollute building water. 污水處理廠常用的外部碳源是甲醇,工業(yè)葡萄糖等。甲醇應(yīng)該是最理想的反硝化補充碳源,但其高成本,高毒性和運輸困難逐漸被其他產(chǎn)品所取代。工業(yè)葡萄糖通常用作額外的碳源。過程測試水質(zhì)測試中心在工業(yè)葡萄糖成分的測量和計算方面做得很好。在實驗室中,以1/100的比例添加工業(yè)葡萄糖,測量COD和BOD含量,并計算每10,000平方米污水的工業(yè)葡萄糖的理論劑量。劑量的劑量是根據(jù)在《給水排水設(shè)計手冊》的第五體積的多級活性污泥法脫氮處理的碳源的計算公式根據(jù)所述過程實驗的結(jié)果計算,并且計算的工業(yè)葡萄糖的劑量。碳源劑量應(yīng)在上限和下限之內(nèi)。上限劑量應(yīng)確保出水COD值不超過標(biāo)準(zhǔn)。下限劑量應(yīng)確保反硝化細(xì)菌的C/N比,以確?偝鏊_(dá)到標(biāo)準(zhǔn)。去除1千克總氮需要4.2千克COD,1千克葡萄糖相當(dāng)于1.1千克COD,因此需要3.9千克葡萄糖才能去除1千克總氮。九公里污水處理廠的日均處理能力為冬季每天20,000平方米,夏季每天50,000平方米。手動添加劑量方法,位置 離緊縮,使顆粒集合穩(wěn)定性下降,分子引力效果下顆粒結(jié)合起來,分散相的簡單陰離子可以被聚合物陰離子基團所替代。 4、洗沙專用聚丙烯酰胺高分子和天然水構(gòu)成中的物質(zhì)和水中懸浮物,或在之前投加的水解混凝劑的離子之間發(fā)生化學(xué)相互效果,可能是絡(luò)合反響。 5、聚丙烯酰胺因為分子鏈固定在不一樣顆粒的表面上,各個固相顆粒之間 毛細(xì)吸水時間(CST)、過濾液的粘度和離心液的粘度。 (2)比阻按考克力(Coackley)提出的實驗辦法,采用布氏漏斗實驗。布氏漏斗的直徑為80mm,濾紙采用由70mm定量中速濾紙,實驗真空度控制為0.01MPa。實驗反復(fù)3次取均勻值。 (3)為了降低比阻,進(jìn)步污泥脫水效果,在污泥脫水前普通均需對污泥中止預(yù)處置。污泥預(yù)處置的辦法有冰凍一凍結(jié)預(yù)處置、熱處置、酸處置、堿處置、石灰預(yù)處置和高分子絮凝劑預(yù)處置等,其中高分子絮凝劑聚丙烯酰胺(PAM) 預(yù)處置是目前國內(nèi)外采用最普遍的預(yù)處置辦法。 (4) 聚丙烯酰胺絮凝劑預(yù)處置普通占整個污泥處置費用較高的比例,因而,聚丙烯酰胺的優(yōu)化選擇和投加率的合理肯定對降低污泥預(yù)處置費用相當(dāng)關(guān)鍵。對選擇聚丙烯酰胺的實驗辦法的研討已展開多年,包括比阻、CST值、污泥流變性、分別液粘度、活動電流等。The synthesis and process physical properties of AM polyacrylamide: PAM is prepared by direct reaction of acrylonitrile with water under the action of framework copper catalyst, and then dried by ion exchange polymerization. The process is as follows: catalyst: catalytic hydration CH2 = CHCN + H2 humidity CH2 = CHCONH2 polymerization nCH2 = CHCONH2 - initiator - CH2CHCONH2 Industrial uses of polyacrylamide: Polyacrylamide (PAM) has high molecular weight, good water solubility, adjustable molecular weight, and can introduce various ionic groups to obtain specific properties. Low molecular weight is an effective additive or stabilizer for dispersing materials. High molecular weight is an important flocculant. It can produce hydrophilic and water-insoluble gel, which has good adhesion to many groups of surface and dissolved substances. Because of the above properties, PAM is widely used in flocculation, thickening, drag reduction, glue imitation, bonding, scale inhibition and other fields. Anionic polyacrylamide can be used in different molecular weights according to different uses and user's requirements for product performance. In industrial wastewater treatment, especially for suspended particles, coarser, high concentration, positive charged particles, neutral and alkaline wastewater such as iron and steel plant wastewater, electroplating plant wastewater, metallurgical wastewater, coal washing wastewater and other wastewater treatment effect is very good. In drinking water treatment. The water source of many Waterworks in our country is low in mud and high in mineral content, which is turbid. Although it has been treated by precipitation, it still can not meet the requirements. Flocculants are needed to make the water quality clear. Many waterworks use inorganic flocculants, but the amount of inorganic flocculants is large, resulting in poor effect of sludge increase. Anionic polyacrylamide acrylamide monomer was 0.012%. The molecular weight of anionic PAM was 12.5 million and the content of acrylamide monomer was 0.013%. The concentration of two kinds of PAM is 0.05%. They are used after refrigeration for 24 hours. (1) PAM pretreatment sludge takes lOml sludge and puts it into a 300 ml beaker. Six-unit mixers are used to mix at 1130 RPM speed for 30 seconds, and then the PAM is added to the sludge quickly and quantitatively. The PAM is stirred at lOOrpm speed for 30 seconds, then the speed of the mixer is reduced to 20-30 rpm and the slow stirring speed is 60 seconds to promote flocculation. The specific resistance of pretreated sludge, capillary water absorption time (CST), the viscosity of filtrate and the viscosity of centrifuge were measured. (2) The specific resistance is tested by Brinell funnel according to the test method proposed by Coackley. The diameter of Brinell funnel is 80 mm. The filter paper is made of 70 mm medium speed filter paper. The vacuum degree of the test is controlled to 0.01 MPa. The experiment was repeated three times to get the average value. (3) In order to reduce specific resistance and improve sludge dewatering effect, sludge should be pretreated before sludge dewatering. Sludge pretreatment methods include freeze-thaw pretreatment, heat treatment, acid treatment, alkali treatment, lime pretreatment and polymer flocculant pretreatment. Polymer flocculant polyacrylamide (PAM) pretreatment is the most widely used pretreatment method at home and abroad. (5)實驗研討標(biāo)明:投加陽離子型和陰離子型PAM后污泥比阻都降低近2個數(shù)量級,顯著改善了污泥的脫水性能。陰離子型PAM投加率為0.3kg/T干污泥,陽離子聚丙烯酰胺絮凝劑的加率為1.5kg/T于污泥,可見陰離子型PAM的投加率遠(yuǎn)小于陽離子型PAM的投加率,且陰離子型PAM的價錢約是陽離子型PAM價錢的1/2,故陰離子型PAM可作為自來水廠污泥預(yù)處置藥劑的首選。 (6)依據(jù)CST值變化肯定PAM最投加率與測定比阻得到的最投加率分歧。并且CST值與比阻之間存在線性相關(guān)關(guān)系,比阻值越大,CST值越大,因而能夠采用CST值來近似替代污泥比阻反映污泥的脫水性能。與比阻相比,cST值測定快速、煩瑣,不但適用于實驗室研討,還可用于消費現(xiàn)場,快速理解污泥脫水性能的變化,使操作人員及時調(diào)楚PAM投加率,儉省藥劑費。is used as flocculant, and the dosage is inorganic flocculant. One fiftieth of the flocculants, but the effect is several times to dozens of times that of inorganic flocculants. Esp ![]() ![]() ![]() ![]() ecially the polyacrylamide produced by our company, the residual monomers have reached the food grade (less than 0.05%), close to the advanced level abroad, non-toxic, more suitable for the treatment of drinking water, and better for the use of organic pollutants polluted river water and anionic polyacrylamide. Polyacrylamide is used to recover lost starch and distiller's grains in starch and alcohol factories. At present, the starch in the waste water discharged by many starch factories is very high. After discharging, it affects the environment, wastes resources, and adds PAM to make starch precipitate. The precipitate is filtered by pressure filter to become cake and can be used as feed. A large number of distillers'grains in the alcohol factories are processed by this process. A certain alcohol factory in Heilongjiang Province uses polyacrylamide as flocculant, which recycles the distillers' grains and obtains a great deal of experience. Economic benefits. Polyacrylamide is used as water shutoff agent for profile control and water shutoff in Oilfield and oil displacement agent for tertiary oil recovery. Polyacrylamide is used as paper-making additive. PAM is widely used in paper-making. It can be used as long fiber paper-making dispersant, wet and dry reinforcing agent, retention aid, filter aid and flocculant of paper-making wastewater. The latest type of water treatment agent polyacrylamide, when treating sewage and water in many occasions, the combination of anionic polyacrylamide and cationic polyacrylamide has a very significant and synergistic effect than using one kind of ionic polyacrylamide alone. The ability of PAM to reduce surface tension is much greater than the ability of cations or anions existing alone under the same conditions. For the requirement of low surface tension, both anionic and cationic polyacrylamide need to be used at the same time. If they are used improperly, white precipitates will be produced and the effect of using them will be lost. PAM has the characteristics of amphoteric ions. It can complete the coordination of anions and cations. There is no precipitate on the surface. Especially, it is more convenient to use PAM as a flocculant because of the complex water quality or the changeable nature of water. The sludge used in sewage pretreatment is taken from the sedimentation tank with Qiantang River water as its source of water, and PAC is used as a flocculant in the water plant. The sludge was naturally concentrated to a solid content of 2.7%-2.8%. The organic matter content in the sludge was 12.1%, SJ content was 52.1%, Al content was determined. The content was 20.2%. There are three types of PAM: cationic, anionic and nonionic. Non-ionic PAM dissolves slowly and is generally not used for sludge pretreatment. Therefore, only two representative cationic polyacrylamides and anionic polyacrylamides are selected in the experiment. The molecular weight of cationic PAM was 12 million and the content of (7)不管是陽離子聚丙烯酰胺絮凝劑還是陰離子聚丙烯酰胺絮凝劑,隨著投加率的增加,濾液和離心液粘度都呈現(xiàn)與比阻和CST值類似的變化規(guī)律,呈現(xiàn)了明顯的最小值,而且該最小值對應(yīng)投加率與污泥比阻和CST值實驗得快速、簡單,而且還有可能用作消費上在線控制PAint最 佳投加率的參數(shù),但其在消費上的應(yīng)用還需做進(jìn)一步的實驗研討。 |
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